Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction.
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The BDFE of a bond A–B can be defined in the same way as the BDE as the standard free energy change (ΔG°) accompanying homolytic dissociation of AB into A and B. However, it is often thought of and computed stepwise as the sum of the free…
Letters to a Young Chemist Letters to a Young Chemist Edited by Abhik Ghosh University of Tromsø, NorwayA John Wile ^ Dougherty, Eric V. Anslyn ; Dennis A. (2006). Modern physical organic chemistry (Dodr. ed.). Sausalito, Calif.: University Science Books. p. 496. ISBN 9781891389313. The Taft equation is a linear free energy relationship (LFER) used in physical organic chemistry in the study of reaction mechanisms and in the development of quantitative structure–activity relationships for organic compounds. In physical organic chemistry, the Grunwald–Winstein equation is a linear free energy relationship between relative rate constants and the ionizing power of various solvent systems, describing the effect of solvent as nucleophile on… ; Myers, Andrew G. (2007). "Chemistry 206 & 215 – Advanced Organic Chemistry Lecture Notes: Lecture Notes, Problem Sets and Exams" (PDF). Harvard Department of Chemistry and Chemical Biology . Retrieved December 27, 2018. Anti or syn indicates the substituents are on opposite sides or the same side, respectively. Clinal substituents are found within 30° of either side of a dihedral angle of 60° (from 30° to 90°), 120° (90°–150°), 240° (210°–270°), or 300… Hammond's postulate (or alternatively the Hammond–Leffler postulate), is a hypothesis in physical organic chemistry which describes the geometric structure of the transition state in an organic chemical reaction.